Considering you can get glue sticks at some craft stores for 10 cents a piece, and 30-40 for huge giant sticks, you could mold from it. You would want to vaseline the heck out of the helmet as a release agent, but I have no clue what type of cast material you would use from there. You could use "rondo" a mix of resin and bondo, but I'm afraid it being so thin, it might just eat away the vaseline, or mix with it and cure onto the hot glue.
Smoothcast 300 might work, but I'm not sure how it cures, everyone uses this stuff to make cast, but i dont know if it has any type of heat reaction when mixed together.