First, use the search function. Tons of topics on this
Mat will give you more strength per layer, but people say cloth is easier to work with. I personaly used one layer of rondo to cast the inside, then one layer of fiberglass mat over that and my pieces are rock solid. I've heard people using cloth for large flat surfaces. I only used cloth when I mudglassed the inside of my back piece on my mk v ce.
Also, I liked using the mat because when I soaked it with a good amount of resin, it was easy to form while when I used cloth it tended to wad and bunch up.
Try both and see what you like best. Its all a matter of your personal preference.
Good luck!