There are some good tutorials out there for home-made vac-forming. It's not as daunting as it may seem.
The most common materials for vacuforming from what I've seen are:
Transparent: PETG, Acrylic, Polycarb
Opaque: Polystyrene, ABS
Of those, Polystyrene and ABS are explicitely NOT food safe. The styrene in them can outgas a little when they're heated, and it will coat your oven and get into your food. I understand styrene to be mutagenic, carcinogenic, and toxic.
For visors, polycarb acrylic and petg are obviously the ones you're looking at. I see some places say polycarb has BPA in it and acrylic is food safe, others that say polycarb is food safe and acrylic melts too easily in food applications. I don't think it's good for me to give out advice on what's SAFE for your oven since I'm a shmoe on a forum. Honestly if it's a serious concern, I'd either get a separate oven, or find someone to vacuform the parts for you. Polycarb is going to need to be baked in your oven a good 1-3 hours before you can pull it, and if it IS releasing chemicals, that's going to thoroughly coat your oven.
I personally favor Acrylic over PETG and Polycarb. Once heat treated for an hour, it pulls very nicely. PETG is cheap and easy to work with but flimsy and cheap-o. Polycarb is strong but TOO stiff and requires a lot of pre-baking before it can be pulled (and it's expensive).
Apparently there's a TAP in Seattle, Lynnwood, and Bellevue WA. If you are ever near those places, it's a good resource for acrylic and polycarb. If you buy from the internet, be aware that while sheets of plastics can say they're for vacuforming, some of them will be so thick that they will either take forever to heat up and pull, or will be so thick they'll lose any details of the object under them (Imagine slapping a thick layer of bondo over an entire helmet, you lose all the details!) I have sheets of 0.125" Acrylic and it's fairly tough to pull with. 0.6" is more than half an inch and I've seen in brochures for nice vacuformers bragging about being able to pull 0.5" plastic like it was an accomplishment, so I would be wary of trying to do that with a home built system.