KYgeLE88, welcome to (the) forums.
In my opinion, while the knife seems like an easy piece to start off with, I don't think it actually is since (like all Pepakura weapons) they are fully enclosed. I'd recommend starting off with a handguard, as they're easy and quick to build, and are similar to other armor pieces in that the reverse side is accessible.
For the record, it's my personal feelings that Pepakura really isn't the best medium to make entire weapons in. Sure, it's very useful to use to make sections of weapons to modify existing parts of toy guns (like NERF guns). However, I think entire weapons are better suited to be made out of "sliced" files (simply combining layers to form something), or shaping it out of wood or foam.
Regarding the resin and order of doing things:
1. Pep the part out of posterboard of similar weight cardboard
2. Put at least 1 coat of resin on the outside to stiffen the cardboard a little more so that it will support the weight of fiberglass. Some people will tell you to put several coats on the outside, but I haven't found this to be necessary.
3. Fiberglass the inside of the piece.
4. Ideally, at this point you use Bondo body filler to smooth out the piece and form curves, etc if required or desired.
5. Paint, finish, padding, and strapping! Finished!
Hope this helps, and if you start building something, you can create a Work-in-progress (WIP) thread where you can aks any more question you may have as they come up.