Don't blame the rondo for that one. It's a well established fact that many glues will dissolve when exposed to the resins in rondo/bondo/fiberglass. It is the fault of the chemical interaction between the glue and the chemicals, and has NOTHING to do with the order in which you lay rondo and fiberglass. In the future, use Hot Glue, PVA Glue, or SuperGlue, as they are established to NOT dissolve when exposed to the compounds in resin and bondo.
Additionally, I would not recommend fiberglassing the OUTSIDE of the helmet, this will obscure details and make modifying it a nightmare. While I applaud you for trying things to see what works for yourself, the conclusions you reached are not correct, and I'd like to help and keep you and anyone else reading from being confused by conflicting information, to save you future headaches when making your suit.
Additionally, I would not recommend fiberglassing the OUTSIDE of the helmet, this will obscure details and make modifying it a nightmare. While I applaud you for trying things to see what works for yourself, the conclusions you reached are not correct, and I'd like to help and keep you and anyone else reading from being confused by conflicting information, to save you future headaches when making your suit.