1) Just wear clothes you won't miss being ruined. You will inevitably get resin on a shirt or pants, and they now become work pants forever! If you are worried, you could go buy some cheap-o pants and shirt, or just use something you won't miss. When you resin, keep a change nearby, because the clothes you resin in will stink for a few hours after.
2) You do apply resin like a paint after you mix it with the hardener. The first layer on the outside and inside should be JUST resin, but in order to harden the helmet you HAVE to use fiberglass cloth/mat with the resin. The resin is pretty fragile on its own, you will be amazed at the different between just resin and resin + fiberglass.
3) You should paint a thin layer on the outside, and maybe a layer on the inside (it helps, but isn't necessary). If you are feeling ambitious, you could pour rondo in the inside first, and then fiberglass it. The resin will hide all of the detailed areas of the helmet, to make laying the fiberglass mat a lot easier, but it is an extra step, and if you cut the fiberglass small enough you don't have to do the rondo, it will just take longer.
2) You do apply resin like a paint after you mix it with the hardener. The first layer on the outside and inside should be JUST resin, but in order to harden the helmet you HAVE to use fiberglass cloth/mat with the resin. The resin is pretty fragile on its own, you will be amazed at the different between just resin and resin + fiberglass.
3) You should paint a thin layer on the outside, and maybe a layer on the inside (it helps, but isn't necessary). If you are feeling ambitious, you could pour rondo in the inside first, and then fiberglass it. The resin will hide all of the detailed areas of the helmet, to make laying the fiberglass mat a lot easier, but it is an extra step, and if you cut the fiberglass small enough you don't have to do the rondo, it will just take longer.